Structure and Reactivity of Alkynyl Ruthenium Alkylidenes
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
Structure and Reactivity of Alkynyl Ruthenium Alkylidenes
应用场景：
创建时间：
2009-01-14
相关数据集
N-Heterocyclic Carbene Palladium Complexes Bearing Carboxylate Ligands and Their Catalytic Activity in the Hydroarylation of Alkynes
The synthesis and reactivity of palladium acetate/trifluoroacetate complexes stabilized by the presence of N-heterocyclic carbene (NHC) ligands are described. The structures and coordination character
NIAID Data Ecosystem70
Selective Cleavage of the C−C Bonds of Aminoethyl Groups, via a Multistep Pathway, by a Pincer Iridium Complex
A pincer-ligated iridium complex is found to react with N-ethylamines, HN(Et)R (R = cyclohexyl, tert-butyl, ethyl), to give the corresponding iridium isocyanide complexes (PCP)Ir(CH3)(H)(CNR) (PCP = κ
NIAID Data Ecosystem70
Structural Characterization and Unique Catalytic Performance of Silyl-Group-Substituted Geminal Dichromiomethane Complexes Stabilized with a Diamine Ligand
Stabilization by a silyl group on the methylene carbon and a diamine ligand led to the isolation of gem-dichromiomethane species. X-ray crystallography confirmed the identity of the structure of this
NIAID Data Ecosystem50
Tantallacarborane Mediated Consecutive C–C and C–N Coupling Reactions of Alkyl Isonitriles: A Facile Route to N‑Heterocycles
Reactions of tantallacarborane methyl complexes ([η1:η5-(Me2NCH2CH2)C2B9H10]TaMe3 (1) and [η1:η5-(MeOCH2CH2)C2B9H10]TaMe3 (8)) with alkyl isonitriles have been studied. Complex 1 reacted with 1 eq
Figshare2016-02-12 更新70
Diastereoselective Synthesis of Dibenzoazepines through Chelation on Palladium(IV) Intermediates
Joint palladium/norbornene organometallic catalysis allows for straightforward access to dibenzo[c,e]azepines. These synthetically challenging polycyclic frameworks form in one pot via a three-compo
NIAID Data Ecosystem60
