Acyclic <i>c</i><i>atena</i>-Diphosphinodiphosphonium Dications [R<sub>3</sub>P-PR‘-PR‘-PR<sub>3</sub>]<sup>2+</sup> or Bisphosphine−Diphosphenium Complexes [R<sub>3</sub>P→PR‘-PR‘←PR<sub>3</sub>]<sup>2+</sup>: Synthesis by Reductive P−P Coupling of [R<sub>3</sub>P-PR‘Cl]<sup>+</sup> and Phosphine Ligand Exchange
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下载链接：
https://figshare.com/articles/dataset/Acyclic_i_c_i_i_atena_i_Diphosphinodiphosphonium_Dications_R_sub_3_sub_P_PR_PR_PR_sub_3_sub_sup_2_sup_or_Bisphosphine_Diphosphenium_Complexes_R_sub_3_sub_P_PR_PR_PR_sub_3_sub_sup_2_sup_Synthesis_by_Reductive_P_P_Coupling_of_R_sub_3_sub_P_PR_Cl_sup_sup_and/3067591
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资源简介：
The acyclic tetraphosphorus dication [Ph3P-PPh-PPh-PPh3]2+ has been formed by the reductive coupling of [Ph3P-PPhCl]+, providing a new synthetic method for the systematic development of catena-phosphorus cations. Ligand exchange (Ph3P for Me3P) gives [Me3P-PPh-PPh-PMe3]2+, implicating these dications as bisphosphine−diphosphenium complexes.
创建时间：
2016-03-01
