CuI Mediated One-Pot Cycloacetalization/Ketalization of <i>o</i>‑Carbonyl Allylbenzenes: Synthesis of Benzobicyclo[3.2.1]octane Core
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https://figshare.com/articles/dataset/CuI_Mediated_One-Pot_Cycloacetalization_Ketalization_of_i_o_i_Carbonyl_Allylbenzenes_Synthesis_of_Benzo_bicyclo_3_2_1_octane_Core/4781128
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资源简介：
CuI/DMSO-mediated
intramolecular cycloacetalization/ketalization
of o-carbonyl allylbenzenes has been achieved for
constructing [6,6,5]-tricycles having a ketal motif in good yields.
The expeditious one-step route provides a three C–O bond formation.
The key products with the structural framework of a benzofused dioxabicyclo[3.2.1]octane
core have been confirmed by X-ray crystallographic analysis. Synthesis
of dihydroisocoumarin has been studied.
创建时间：
2017-03-23
