Rh(III)-Catalyzed Dual C–H Functionalization/Cyclization Cascade by a Removable Directing Group: A Method for Synthesis of Polycyclic Fused Pyrano[<i>de</i>]Isochromenes
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https://figshare.com/articles/dataset/Rh_III_-Catalyzed_Dual_C_H_Functionalization_Cyclization_Cascade_by_a_Removable_Directing_Group_A_Method_for_Synthesis_of_Polycyclic_Fused_Pyrano_i_de_i_Isochromenes/12977004
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资源简介:
An
interesting Rh(III)-catalyzed dual C–H functionalization/cyclization
cascade of azomethine imine with diazophosphonate by a removable directing
group for the synthesis of highly fused pyrano[de]isochromene has been achieved. The transformation shows that the
desired pyrano[de]isochromenes with two oxygen atoms
on its core scaffold could be constructed with good to excellent yields
(up to 86%) via a facile one-pot, multiple-step cascade
reaction, along with broad generality and versatility.
创建时间:
2020-09-07



