Ring-Opening Polymerization of a Strained [3]Nickelocenophane: A Route to Polynickelocenes, a Class of <i>S</i> = 1 Metallopolymers
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https://figshare.com/articles/dataset/Ring_Opening_Polymerization_of_a_Strained_3_Nickelocenophane_A_Route_to_Polynickelocenes_a_Class_of_i_S_i_1_Metallopolymers/2303470
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资源简介:
We report the synthesis, reactivity
studies, and ring-opening polymerization
of a tricarba[3]nickelocenophane. The resulting
green polynickelocene (5) possesses a -(CH2)3- spacer between the nickelocene units and is
shown to be of high molecular weight. SQUID magnetometry measurements
indicate that 5 is a macromolecular material with an S = 1 repeat unit.
创建时间:
2016-02-17



