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Hydrogen Bond Templated 1:1 Macrocyclization through an Olefin Metathesis/Hydrogenation Sequence

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Hydrogen_Bond_Templated_1_1_Macrocyclization_through_an_Olefin_Metathesis_Hydrogenation_Sequence/2395090
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The construction of pyridine-containing macrocyclic architectures using a nonmetallic template is described. 4,6-Dichlororesorcinol was used as an exotemplate to self-organize two aza-heterocyclic units by OH···N hydrogen bonds. Subsequent sequential double olefin metathesis/hydrogenation reactions employing a single ruthenium–alkylidene precatalyst open access to macrocyclic molecules.
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2016-02-19
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