Pd-Catalyzed Sequential C–C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species
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下载链接：
https://figshare.com/articles/dataset/Pd_Catalyzed_Sequential_C_C_Bond_Formation_and_Cleavage_Evidence_for_an_Unexpected_Generation_of_Arylpalladium_II_Species/2504437
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资源简介：
A Pd(II)-catalyzed reaction engaging alkenyl β-keto
esters
is reported that leads to the formation of 1-naphthols and an unexpected
generation of arylpalladium(II) species. Interception of the in situ
generated arylpalladium(II) species in a Mizoroki–Heck reaction,
together with additional mechanistic studies, provided strong evidence
in support of the first aromatization-driven β-carbon
elimination process. A single Pd catalyst served to promote a series
of both C–C bond forming and cleavage events in an unprecedented
manner.
创建时间：
2012-07-18
