Pd−N−H···Cl−Pd Hydrogen Bonds and π−π Interactions between Fluorinated Aromatic Rings in <i>trans</i>-[PdCl<sub>2</sub>(NH<sub>2</sub>Ar<sup>F</sup>)<sub>2</sub>]
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https://figshare.com/articles/dataset/Pd_N_H_Cl_Pd_Hydrogen_Bonds_and__Interactions_between_Fluorinated_Aromatic_Rings_in_i_trans_i_PdCl_sub_2_sub_NH_sub_2_sub_Ar_sup_F_sup_sub_2_sub_/3034882
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资源简介：
The molecular and crystal structures of a series of fluoro-aniline complexes of general formula trans-[PdCl2(NH2ArF)2], with ArF = C6H3-2,3-F2 (1), C6H3-2,5-F2 (2), C6H3-3,4-F2 (3), C6H3-3,5-F2 (4), C6H2- 2,3,4-F3 (5), C6H2-2,4,5-F3 (6), C6H2-2,4,6-F3 (7), were determined. Analysis of these structures demonstrate that robust reliable supramolecular synthons are obtained
through Pd−N−H···Cl−Ph hydrogen-bond interactions. The possible influence of the polarization of the different ArF aromatic
rings in the arrangement of the molecules within the hydrogen-bonded structures is discussed.
创建时间：
2007-01-03
