X-ray and Neutron Diffraction Studies on “Li_4.4Sn”

A chemical analysis and detailed structural characterization, using X-ray single crystal and neutron powder diffraction,
of the binary lithium−tin compound “Li4.4Sn” is presented. Phase analyses and subsequent structural refinements
result in the reformulation of “Li4.4Sn” as Li17Sn4. The lithium-rich binary phase crystallizes with a complex cubic
structure in the space group F4̄3m, with a = 19.6907(11) Å, Z = 20. The improved crystal structure determination
indicates well-defined lithium atom positions, some of which differ from those previously reported. The nearly Zintl
phase Li17Sn4 exhibits poor metallic behavior similar to that of heavily doped semiconductors. Comparisons of the
refined crystal structure with previously reported X-ray crystal structures associated with “Li4.4Sn” are discussed.