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Exploring Morita−Baylis−Hillman Reactions of <i>p</i>-Quinols

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Exploring_Morita_Baylis_Hillman_Reactions_of_i_p_i_Quinols/2794324
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The Morita−Baylis−Hillman reaction of p-methylquinols with activated aromatic aldehydes has been studied. Depending on the reaction conditions (solvent and additives), three different products were formed. A mono or double Morita−Baylis−Hillman adduct and a fused 1,3-dioxolane could be obtained in good chemical yields. The use of non-nucleophilic bases to promote the reaction suggested an autocatalytic mechanism.
创建时间:
2010-02-05
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