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Isolation and X-ray Structures of Labile Benzoic- and Acetic-Acidium Carbocations

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Isolation_and_X_ray_Structures_of_Labile_Benzoic_and_Acetic_Acidium_Carbocations/3291028
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New carbocationic salts (via O-protonation of substituted benzoic acids) are prepared for the first time by controlled hydration of the corresponding benzoylium salts and isolated in pure crystalline form. Precise X-ray structural analyses reveal the rather unexpected (electronic) structure of the carboxylic-acidium functionality.
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2016-05-06
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