Template Synthesis of Decaphyrin without <i>Meso</i>-Bridges: Cyclo[10]pyrrole
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https://figshare.com/articles/dataset/Template_Synthesis_of_Decaphyrin_without_i_Meso_i_-Bridges_Cyclo_10_pyrrole/3423581
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资源简介：
An acenaphthylene-fused
cyclo[10]pyrrole 1b was selectively
synthesized via an oxidative coupling reaction of the corresponding
2,2′-bipyrrole with the appropriate dianion template, croconate
anion. The structure of 1b as the isolated largest cyclo[n]pyrrole was elucidated by X-ray crystallographic analysis.
The absorption spectrum exhibited a markedly red-shifted, intensified
L band at 1982 nm, which was interpreted by application of Michl’s
perimeter and Gouterman’s 4-orbital models, supported by magnetic
circular dichroism (MCD) data and theoretical calculations.
创建时间：
2016-06-17
