Direct Observation of Oxidative Cyclization of η<sup>2</sup>-Alkene and η<sup>2</sup>-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of Me<sub>3</sub>SiOTf
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Direct oxidative cyclization of (η2:η2-CH2CHCH2C6H4CHO)Ni(PR3) to form the nickelacycle and drastic acceleration of the cyclization by the addition of Me3SiOTf were observed. (η2-PhCHO)Ni(PCy3)2 also reacted with Me3SiOTf to give (η:η1-Me3SiOCH(Ph))Ni(PCy3)OTf.
创建时间:
2004-09-29



