Synthesis of Hexa(furan-2-yl)benzenes and Their π‑Extended Derivatives
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https://figshare.com/articles/dataset/Synthesis_of_Hexa_furan_2_yl_benzenes_and_Their_Extended_Derivatives/2433730
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The first synthesis of hexa(furan-2-yl)benzene derivatives is described. The RhCl3/i-Pr2NEt-catalyzed cyclotrimerization of di(furan-2-yl)acetylenes was an effective method for constructing hexa(furan-2-yl)benzene derivatives in good yields. Their π-extended derivatives were also synthesized by Suzuki–Miyaura coupling between hexakis(5-Bpinfuran-2-yl)benzene (Bpin = (pinacolato)boryl) and several aryl iodides.
创建时间:
2016-02-19



