Hydrogenation of Esters Catalyzed by Ruthenium PN3‑Pincer Complexes Containing an Aminophosphine Arm
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Hydrogenation of esters under mild conditions was achieved using air-stable ruthenium PN3-pincer complexes containing an aminophosphine arm. High efficiency was achieved even in the presence of water. DFT studies suggest a bimolecular proton shuttle mechanism which allows H2 to be activated by the relatively stable catalyst with a reasonably low transition state barrier.
创建时间：
2016-02-17
