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NMR Hahn echo decays in deuterated polyethylene oxide melts

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DataCite Commons2025-06-01 更新2024-07-29 收录
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This dataset contains the raw and processed <sup>2</sup>H NMR relaxation data from Hahn echo (HE) and inversion recovery (IR) experiments in deuterated polyethylene oxide melts of different molar masses (3.5kDa, 33kDa, 75kDa and 300kDa) at different temperatures (55/60°C, 70°C, 85°C and 100°C). The PEO-d<sub>4</sub> samples were placed in 3mm outer diameter NMR glass tubes, covered with Argon and flame sealed. The measurements were performed on a Bruker Avance III NMR spectrometer at a <sup>2</sup>H resonance frequency of 46.1 MHz. In addition, matlab scripts to extract the effective transverse relaxation time and to calculate the decay predicted by the Rouse and tube-reptation model taking the effects of dynamical heterogeneity into account (see 10.1063/5.0099293) are included in this dataset.

提供机构:
figshare
创建时间:
2022-07-29
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