Stereoselective Syntheses of the 2-Isopropenyl-2,3-dihydrobenzofuran Nucleus: Potential Chiral Building Blocks for the Syntheses of Tremetone, Hydroxytremetone, and Rotenone
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https://figshare.com/articles/dataset/Stereoselective_Syntheses_of_the_2_Isopropenyl_2_3_dihydrobenzofuran_Nucleus_Potential_Chiral_Building_Blocks_for_the_Syntheses_of_Tremetone_Hydroxytremetone_and_Rotenone/3013009
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资源简介：
The first enantioselective synthesis of the 2-isopropenyl-2,3-dihydrobenzofuran skeleton of tremetone
and hydroxytremetone from (E)-4-(2-hydroxyphenyl)-2-methyl-2-butenyl methyl carbonate and (E)-4-(2,6-dihydroxyphenyl)-2-methyl-2-butenyl methyl carbonate, respectively, is described. The key step is
a catalytic palladium-mediated reaction in the presence of the chiral Trost ligand.
创建时间：
2016-02-29
