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N-hydroxyphthalimidyl diazoacetate (NHPI-DA): a modular methylene linchpin for the C–H alkylation of indoles

NIAID Data Ecosystem2026-03-12 收录

有机合成方法

吲哚C-H烷基化

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https://zenodo.org/record/4652792 数据链接链接失效反馈

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资源简介：

NMR and HRMS of the new compounds in the publication cited.

应用场景：

创建时间：

2021-04-01

烯丙基C-H键活化

有机合成方法

A general method for intermolecular allylic C–H alkylation of terminal olefins with tertiary nucleophiles has been accomplished employing palladium(II)/bis(sulfoxide) catalysis. Allylic C–H alkylati

NIAID Data Ecosystem50

Two Approaches to the Aromatic Core of the Aminonaphthoquinone Antibiotics

萘醌抗生素合成

有机合成方法

Two complementary approaches are presented for the synthesis of the quinone chromophores of the naphthoquinone ansamycins and related natural products. The first involves the use of an improved protoc

NIAID Data Ecosystem40

Synthesis of (±)-Idarubicinone via Global Functionalization of Tetracene

药物合成

有机合成方法

Anthracyclines are archetypal representatives of the tetracyclic type II polyketide natural products that are widely used in cancer chemotherapy. Although the synthesis of this class of compounds has

NIAID Data Ecosystem30

Diastereoselective Synthesis of Double Axially Chiral Indole Derivatives via Friedel–Crafts Biarylation

有机合成方法

手性吲哚合成

We report a copper-catalyzed Friedel–Crafts biarylation protocol that delivers C3-site-selective doubly axially chiral biaryl indoles using five-membered cyclic diaryliodonium salts as biarylating age

Figshare2026-03-10 更新40

Rauhut–Currier Reaction of Nitroalkenes with Vinyl Phosphonates: A Route to Electron Deficient Skipped Dienes

有机合成方法

非共轭二烯合成

We have established an efficient transition metal-free protocol for the synthesis of activated, functionalized terminal nonconjugated 1,4-dienes (skipped dienes) via Horner–Wadsworth–Emmons (HWE) olef

Figshare30

N-hydroxyphthalimidyl diazoacetate (NHPI-DA): a modular methylene linchpin for the C–H alkylation of indoles

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