Formation of a Novel P,C-Cage Ligand via a <i>P</i>-C<sub>5</sub>Me<sub>5</sub>-Substituted Li/Cl Phosphinidenoid Complex
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The novel P,C-cage ligand in the dinuclear tungsten complex 3 was obtained by reaction of the Li/Cl phosphinidenoid complex 2, characterized by NMR spectroscopy, at low temperature; complex 3 was characterized by elemental analysis and NMR, IR, and MS studies and by single-crystal X-ray diffraction.
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2009-08-24
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