Iron-Catalyzed Hydroboration of Vinylcyclopropanes
收藏NIAID Data Ecosystem2026-03-10 收录
下载链接：
https://figshare.com/articles/dataset/Iron-Catalyzed_Hydroboration_of_Vinylcyclopropanes/5449699
下载链接
链接失效反馈官方服务：
资源简介：
An
iron-catalyzed hydroboration of vinylcyclopropane with HBpin
is first reported for the preparation of valuable homoallylic organoboronic
esters. The iron catalysts enable efficient and regioselective C–C
cleavage of vinylcyclopropanes, stereoselectively delivering E-alkenes with good stereospecific selectivity at an allylic
position. This protocol exhibits mild conditions with good functional
group tolerability. The chiral homoallylic organoboronic esters could
be further converted into chiral polysubstituted tetrahydrofuran and
tetrahydropyran.
创建时间：
2017-09-27
