π-Extension in Expanded Porphyrins: Cyclo[4]naphthobipyrrole
收藏Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_Extension_in_Expanded_Porphyrins_Cyclo_4_naphthobipyrrole/2597926
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The π-extended cyclo[4]naphthobipyrrole 1a has been prepared via an Fe(III)-mediated oxidative cyclization of an alkyl-substituted naphthobipyrrole. The structure of this new expanded porphyrin, isolated as the deprotonated sulfate salt, was characterized by spectroscopic means, as well through a single crystal X-ray diffraction analysis. Salt 1a displays a total of four well-resolved redox waves as determined by cyclic voltammetry. It also displays bathochromically shifted near-IR absorption maxima compared to the diprotonated forms of nonannulated cyclo[8]pyrroles.
创建时间：
2016-02-22
