Cleavage of the Carbon−Sulfur Bonds in Thiophenes by a Binuclear Ruthenium Complex
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https://figshare.com/articles/dataset/Cleavage_of_the_Carbon_Sulfur_Bonds_in_Thiophenes_by_a_Binuclear_Ruthenium_Complex/3784056
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资源简介:
The dinuclear polyhydride [Cp*RuH2]2 (Cp*
= C5Me5) reacts with thiophene at ambient temperature
to give a C−S ring-opened “flyover” complex in which
all atoms are bound to the metal centers. A similar
reaction with 2-methylthiophene also gives a related
product. The products were characterized by single-crystal X-ray diffraction.
创建时间:
2016-08-27



