Molecular Iodine Promoted Divergent Synthesis of Benzimidazoles, Benzothiazoles, and 2‑Benzyl-3-phenyl-3,4-dihydro‑2<i>H</i>‑benzo[<i>e</i>][1,2,4]thiadiazines
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An unprecedented formation of a new class of 2-benzyl-3-phenyl-3,4-dihydro-2H-benzo[e][1,2,4]thiadiazines has been discovered during the course of benzimidazole and benzothiazole synthesis, through the molecular iodine-mediated oxidative cyclization with a new C–N and S–N bond formation at ambient temperature.
创建时间:
2016-02-17



