Zinc(II)-Mediated Carbene Insertion into C–H Bonds in Alkanes
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https://figshare.com/articles/dataset/Zinc_II_Mediated_Carbene_Insertion_into_C_H_Bonds_in_Alkanes/2102464
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资源简介：
The
cationic zinc adduct {[HB(3,5-(CF3)2Pz)3]Zn(NCMe)2}ClO4 catalyzes the functionalization
of tertiary, secondary, and primary C–H bonds of alkanes via
carbene insertion. Ethyl diazoacetate serves as the :CHCO2Et carbene precursor. The counteranion, supporting ligand, and coordinating
solvents affect the catalytic activity. An in situ generated {[HB(3,5-(CF3)2Pz)3]Zn}+ species containing
a bulkier {B[3,5-(CF3)2C6H3]4}− anion gives the best results among
the zinc catalysts used.
创建时间：
2017-12-28
