Fluorescent Uranyl Ion Lidded Cucurbit[5]uril Capsule
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https://figshare.com/articles/dataset/Fluorescent_Uranyl_Ion_Lidded_Cucurbit_5_uril_Capsule/2567002
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资源简介:
A novel fluorescent complex {(UO2)2(CB5)}(NO3)4·4HNO3.3H2O (U2CB5)
is obtained from cucurbit[5]uril (CB5) and uranyl nitrate under ambient
temperature conditions. The crystal structure revealed that two uranyl
ions are coordinated to the two open portals of CB5 giving a closed
molecular capsule, which further connected through CB5 molecules to
give two-dimensional frameworks. The U2CB5 complex was further investigated
by NMR, FTIR and TGA techniques. The Fluorescence of uranyl ion was
found to be enhanced due to complexation with cucurbituril.
创建时间:
2012-01-02



