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Addition of Diazo Compounds ipso-C–H Bond to Carbon Disulfide: Synthesis of 1,2,3-Thiadiazoles under Mild Conditions

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Figshare2018-03-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Addition_of_Diazo_Compounds_i_ipso_i_-C_H_Bond_to_Carbon_Disulfide_Synthesis_of_1_2_3-Thiadiazoles_under_Mild_Conditions/6011030
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We describe here an operationally simple and straightforward synthesis method for a series of diverse 4,5-disubstituted 1,2,3-thiadiazoles via the nucleophilic addition of α-diazo carbonyl compounds to carbon disulfide. This method features using abundant and inexpensive carbon disulfide under mild reaction conditions.
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2018-03-21
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