Gas Adsorption, Magnetism, and Single-Crystal to Single-Crystal Transformation Studies of a Three-Dimensional Mn(II) Porous Coordination Polymer
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https://figshare.com/articles/dataset/Gas_Adsorption_Magnetism_and_Single_Crystal_to_Single_Crystal_Transformation_Studies_of_a_Three_Dimensional_Mn_II_Porous_Coordination_Polymer/2238955
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资源简介：
A porous coordination polymer {[Mn2(DBIBA)3]NO3·3DMF·4H2O}n (1) [DBIBAH =
3,5-di(1H-benzo[d]imidazol-1-yl)benzoic
acid] has been synthesized
solvothermally and structurally characterized by single-crystal X-ray
diffraction. The following four new coordination polymers {[Mn2(DBIBA)3]·ClO4·DMF·H2O}n (2), {[Mn2(DBIBA)3]·Cl·DMF·8H2O}n (3), {[Mn2(DBIBA)3]·NO3·CH3OH·5H2O}n (4) and {[Mn2(DBIBA)3]·NO3·3CH3COCH3·7H2O}n (5) have been
synthesized from 1 via anion/solvent exchange protocols
in a single-crystal to single-crystal fashion at room temperature.
Gas sorption studies for desolvated compounds 1, 2, and 3 show that CO2 uptake capacity
is entirely dependent upon the size of the anion present in the framework.
Complex 1 also exhibits antiferromagnetic properties
below 17 K, confirmed through magnetic susceptibility measurements.
创建时间：
2016-02-16
