Synthesis and Characterization of a Novel Cobalt Carbonyl N-Heterocyclic Carbene Salt. Crystal Structure of [Co(CO)<sub>3</sub>(IMes)<sub>2</sub>]<sup>+</sup>[Co(CO)<sub>4</sub>]<sup>-</sup>
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资源简介：
The disproportionation of dicobalt octacarbonyl induced by the free carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) and the X-ray characterization of the cyclohexane solvate of the resulting cobalt carbonyl N-heterocyclic carbene salt, [Co(CO)3(IMes)2]+[Co(CO)4] -·1/4C6H12, is reported. The crystal structure represents the first example of a [Co(CO)3(L)2][Co(CO)4] disproportionate salt reported to date.
创建时间：
2016-02-29
