Rare-Earth Iodides in Ionic Liquids: The Crystal Structure of [SEt<sub>3</sub>]<sub>3</sub>[LnI<sub>6</sub>] (Ln = Nd, Sm)
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Crystals of [SEt3]3[LnI6] (Ln = Nd, Sm) were obtained by the reaction of LnI2 with the ionic liquid [SEt3][Tf2N] [Tf2N = bis(trifluoromethanesulfonyl)imide]. The compounds are characterized by octahedral [LnI6]3- units that are surrounded by a distorted cube of triethylsulfonium cations.
创建时间:
2016-05-05



