Paramagnetic–Diamagnetic Phase Transition Accompanied by Coordination Bond Formation–Dissociation in the Dithiolate Complex Na[Ni(pdt)2]·2H2O
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Paramagnetic_Diamagnetic_Phase_Transition_Accompanied_by_Coordination_Bond_Formation_Dissociation_in_the_Dithiolate_Complex_Na_Ni_pdt_sub_2_sub_2H_sub_2_sub_O/2629706
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Bis(2,3-pyrazinedithiolate)nickel complex Na[Ni(pdt)2]·2H2O formed one-dimensional stacks of the Ni(pdt)2 units and showed strong antiferromagnetic interactions along the stacking direction. A first-order phase transition between the paramagnetic and diamagnetic states, which was driven by dimerization of the Ni(pdt)2 units, accompanied by coordination bond formation, was observed.
创建时间：
2016-02-23
