Paramagnetic–Diamagnetic Phase Transition Accompanied by Coordination Bond Formation–Dissociation in the Dithiolate Complex Na[Ni(pdt)2]·2H2O
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资源简介：
Bis(2,3-pyrazinedithiolate)nickel complex Na[Ni(pdt)2]·2H2O formed one-dimensional stacks of the Ni(pdt)2 units and showed strong antiferromagnetic interactions along the stacking direction. A first-order phase transition between the paramagnetic and diamagnetic states, which was driven by dimerization of the Ni(pdt)2 units, accompanied by coordination bond formation, was observed.
创建时间：
2016-02-23
