New 3-D Chiral Framework of Indium with 1,3,5-Benzenetricarboxylate
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https://figshare.com/articles/dataset/New_3_D_Chiral_Framework_of_Indium_with_1_3_5_Benzenetricarboxylate/3305443
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资源简介：
A new complex, [In2(μ-OH)2(btc)2]n·2nHpy (1) (btc = 1,3,5-benzenetricarboxylate; py = pyridine), is hydrothermally
synthesized from the reaction of InCl3, H3btc, and pyridine. Complex 1 crystallizes in the monoclinic P21 space
group [a = 7.3181(12) Å, b = 17.0195(23) Å, c = 10.5789(17) Å, β = 102.651(6)°, and Z = 2]. Indium(III)
centers in 1 are bridged by btc ligands in various coordination modes to form the nonclose rings which are further
interlinked along crystallographic a-axis and (011) plane to result in a nonpenetrated 3-D anionic framework growing
as homochiral tunnels. Compound 1 is fully characterized by fluorescence spectroscopy, second harmonic generation
measurement, infrared, and thermogravimetric analysis.
创建时间：
2016-05-06
