Advances in Lewis Acid Controlled Carbon−Carbon Bond-Forming Reactions Enable a Concise and Convergent Total Synthesis of Bullatacin
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https://figshare.com/articles/dataset/Advances_in_Lewis_Acid_Controlled_Carbon_Carbon_Bond_Forming_Reactions_Enable_a_Concise_and_Convergent_Total_Synthesis_of_Bullatacin/3059695
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资源简介:
Lewis acids control regioselectivity in the alkylation of epi-chlorohydrin and the stereochemistry of an alkyne addition to set the C24/C23 anti
relationship. These advances facilitate an efficient total synthesis of bullatacin in 13.3% overall yield from commercial starting materials.
创建时间:
2006-09-14



