Ferrocene-Appended Aryl Triazole for Electrochemical Recognition of Phosphate Ions
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A neutral ferrocene-appended aryl triazole receptor 1 for phosphate anions has been synthesized and characterized by X-ray crystal analysis. Among various anions, 1 shows a distinct electrochemical recognition of phosphate anions by its multiple H-bonding (C–H···O) with a tetrahedral anion, which is supported by density functional theory based theoretical calculation and 1H NMR titration results.
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2011-08-19
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