Luminescent Li-Based Metal–Organic Framework Tailored for the Selective Detection of Explosive Nitroaromatic Compounds: Direct Observation of Interaction Sites
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https://figshare.com/articles/dataset/Luminescent_Li_Based_Metal_Organic_Framework_Tailored_for_the_Selective_Detection_of_Explosive_Nitroaromatic_Compounds_Direct_Observation_of_Interaction_Sites/2450536
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资源简介：
A luminescent lithium metal–organic framework
(MOF) is constructed from the solvothermal reaction of Li+ and a well-designed organic ligand, bis(4-carboxyphenyl)-N-methylamine (H2CPMA). A Li-based MOF can detect
an explosive aromatic compound containing nitro groups as an explosophore,
by showing a dramatic color change with concurrent luminescence quenching
in the solid state. The detection sites are proven directly through
single-crystal-to-single-crystal transformations, which show strong
interactions between the aromatic rings of the electron-rich CPMA2– molecules and the electron-deficient nitrobenzene.
创建时间：
2016-02-20
