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Highly π-Extended TTF Analogues with a Conjugated Macrocyclic Enyne Core

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https://figshare.com/articles/dataset/Highly_Extended_TTF_Analogues_with_a_Conjugated_Macrocyclic_Enyne_Core/2956189
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The synthesis of a class of highly π-extended tetrathiafulvalene derivatives (1a and 1b) was explored using Sonogashira macrocyclization as a key step. The solid-state structure of 1b was characterized by X-ray single crystallography, showing a substantially bent, S-shaped molecular backbone and an ordered packing geometry in a π-alkyl−alkyl-π stacking fashion. Electronic and redox properties of 1b were investigated by UV−vis absorption, fluorescence spectroscopy, and cyclic voltammetry.
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2016-06-03
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