Divalent Ytterbium Boratabenzene Complex (C<sub>5</sub>H<sub>5</sub>BNPh<sub>2</sub>)<sub>2</sub>Yb(THF)<sub>2</sub>: Synthesis, Structure, and Solvent-Mediated Redox Transformation
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The boratabenzene derivative of divalent ytterbium complex (C5H5BNPh2)2Yb(THF)2 (1) was synthesized and characterized. Reaction of 1 with α-diimine PhNC(Me)C(Me)NPh in toluene afforded a trivalent ytterbium complex, [C5H5BNPh2]2Yb[PhNC(Me)C(Me)NPh] (2), which was characterized by single-crystal X-ray diffraction. The redox process is solvent sensitive and reversible.
创建时间：
2008-08-11
