Slow Relaxation Processes and Single-Ion Magnetic Behaviors in Dysprosium-Containing Complexes

A series of one-dimensional complexes [Ln(L1)3(HOCH2CH2OH)]n (L1 = 2-furoate anion; Ln = Nd (1), Sm (2), Gd (3), Tb (4), Dy (5), Er (6)) have been synthesized. The complexes were crystallized in the monoclinic space group P2(1)/c and show a chain-like structure determined by single-crystal X-ray diffraction. Magnetic properties indicate that carboxyl group of 2-furoate mediates different magnetic couplings in light and heavy rare earth complexes, namely, antiferromagnetic interaction between light rare earth ions and ferromagnetic interaction between heavy ones. Noticeably, complex 5 displays a strong frequency dependence of alternating current (AC) magnetic properties. Further magnetic studies show a distribution of a single relaxation process in 5. While 1,10-phenanthroline and phthalate anion (L2) were employed, [Dy2(L2)6(H2O)]n (7) was isolated by hydrothermal reactions and characterized magnetically. Research results also show the frequency dependence of AC magnetic susceptibilities, although the phthalate anions mediate antiferromagnetic coupling between DyIII ions. Further magnetic investigation of a neutral mononuclear complex with the formula [Dy(TTA)3(L3)] (8) (TTA = 2-thenoyltrifluoroacetonate; L3 = 4,5-pinene bipyridine) suggests that the single-ion magnetic behavior originates the slow relaxation of DyIII-containing complexes.