Co(II)−Co(II) Paddlewheel Complex with a Redox-Active Ligand Derived from TTF
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https://figshare.com/articles/dataset/Co_II_Co_II_Paddlewheel_Complex_with_a_Redox_Active_Ligand_Derived_from_TTF/3039571
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资源简介：
A new trimethyltetrathiafulvalene (Me3TTF) derivative Me3TTF−CHCH−py bearing a pyridyl was synthesized and coordinated
to a cobalt(II) benzoate dimer, having paddlewheel core structure,
leading to a complex formulated as Co2(PhCOO)4(Me3TTF−CHCH−py)2. Single-crystal X-ray diffraction studies of the complex
performed at 293 and 100 K evidenced the existence of a weak
metal−metal interaction. Magnetic studies revealed an antiferromagnetic behavior, which is explained as the result of the direct
exchange between metal centers.
创建时间：
2016-02-29
