Multifunctional Zn(II) Complexes: Photophysical Properties and Catalytic Transesterification toward Biodiesel Synthesis
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https://figshare.com/articles/dataset/Multifunctional_Zn_II_Complexes_Photophysical_Properties_and_Catalytic_Transesterification_toward_Biodiesel_Synthesis/3493001
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资源简介：
Using 4-substituted
derivatives of phenol-based compartmental Schiff-base hydroxyl-rich
ligand, four multifunctional binuclear Zn(II) complexes have been
synthesized and characterized. The photophysical properties of these
complexes were explored in the solid state, in solutions, and in poly(methyl
methacrylate) (PMMA) matrix, which revealed their good potential as
tunable solid state emitters. Some of these complexes acted as efficient
catalysts for the transesterification of esters and canola oil showing
their potential in biodiesel generation. Mechanistic investigations
using ESI-MS revealed that the transesterification catalyzed by these
complexes proceeds through two types of acyl intermediates.
创建时间：
2016-07-26
