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Asymmetric Dearomatization of 1‑Aminonaphthalene Derivatives by Gold-Catalyzed Intramolecular Double C–C Bond Formation

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Figshare2016-02-15 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Asymmetric_Dearomatization_of_1_Aminonaphthalene_Derivatives_by_Gold_Catalyzed_Intramolecular_Double_C_C_Bond_Formation/2208961
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It has been established that a cationic gold­(I)/axially chiral biaryl bisphosphine complex catalyzes asymmetric dearomatization of 1-aminonaphthalene derivatives by the intramolecular double C–C bond formation. Two different dearomatization products were obtained depending on the substituents on the benzyl groups at the alkyne termini.
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2016-02-15
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