Palladium-Catalyzed Vinylation of Aminals with Simple Alkenes: A New Strategy To Construct Allylamines
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Vinylation_of_Aminals_with_Simple_Alkenes_A_New_Strategy_To_Construct_Allylamines/2457490
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资源简介：
A novel, highly selective palladium-catalyzed vinylation
reaction
for the direct synthesis of allylic amines from styrenes and aminals
has been established. The utility of this method was also demonstrated
by the rapid synthesis of cinnarizine from aldehydes, amines, and
simple alkenes in one-pot manner. Mechanistic studies suggested that
the reaction proceeds through a valuable cyclometalated Pd(II) complex
generated by the oxidative addition of aminal to a Pd(0) species.
创建时间：
2016-02-20
