Bimetallic Octahedral Ruthenium–Nickel Carbido Cluster Complexes. Synthesis and Structural Characterization
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Bimetallic_Octahedral_Ruthenium_Nickel_Carbido_Cluster_Complexes_Synthesis_and_Structural_Characterization/2437894
下载链接
链接失效反馈官方服务：
资源简介：
The reaction of Ru5(CO)15(μ5-C) with Ni(COD)2 in acetonitrile
at 80 °C
affords the bimetallic octahedral ruthenium–nickel cluster
complex Ru5Ni(NCMe)(CO)15(μ6-C), 3. The acetonitrile ligand in 3 can be replaced by CO and NH3 to yield Ru5Ni(CO)16(μ6-C), 4, and Ru5Ni(NH3)(CO)15(μ6-C), 5, respectively. Photolysis
of compound 3 in benzene and toluene solvent yielded
the η6-coordinated benzene and toluene Ru5Ni carbido cluster complexes Ru5Ni(CO)13(η6-C6H6)(μ6-C), 6, and Ru5Ni(CO)13(η6-C7H8)(μ6-C), 7, respectively. All five new compounds
were structurally characterized by single-crystal X-ray diffraction
analyses.
创建时间：
2016-02-19
