Single-Molecule-Magnet Behavior in a Fe<sub>12</sub>Sm<sub>4</sub> Cluster
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Through the combination of SmIII spin carriers with a FeIII system, the largest Fe−Ln cluster so far has been synthesized. To our knowledge, the new complex, Fe12Sm4, is the first SmIII single-molecule magnet. Furthermore, Fe12La4 and Fe12Gd4 have also been synthesized to help understand the magnetic exchange interactions and origin of magnetic anisotropy in Fe12Sm4.
创建时间：
2010-11-01
