Selective cleavage of an inert C–C bond followed by C–O/N bond formation through a long-distance aryl migration from a carbon to a nitrogen center via Ag catalysis is reported. The migration products
Copper-catalyzed intramolecular vinylation of iodoenamides were investigated for the first time. With CuI as the catalyst and N,N‘-dimethylethylenediamine as the ligand, a number of iodoenamides under
Herein, we report a photocatalytic redox-neutral dehydration of native aryl-1,2-ethanediols to aryl methyl ketones. This mild reaction can be realized with a single organic photocatalyst and yields wa
An unexpected Cu-catalyzed oxidative cleavage of the C(sp3)–C(sp3) bond in glycol ethers by using air or molecular oxygen as the terminal stoichiometric oxidant is demonstrated. As a result, the corre
An intermolecular three-component arylsilylation of alkynes has been developed under mild palladium/copper cooperative catalysis. The reaction proceeds through syn-addition of an aryl group and a sily
