Synthesis and Characterization of Fused Pyrrolo[3,2-<i>d</i>:4,5-<i>d′</i>]bisthiazole-Containing Polymers
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The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d′]bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors.
创建时间:
2010-12-03



