Aluminum–Amido-Mediated Heterolytic Addition of Water Affords an Alumoxane
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https://figshare.com/articles/dataset/Aluminum_Amido_Mediated_Heterolytic_Addition_of_Water_Affords_an_Alumoxane/2350621
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资源简介：
Addition
of the O–H bonds in water across the aluminum–nitrogen
bond of a molecular aluminum–amido complex affords an alumoxane.
The reaction of (PhI2P2–)AlH
(1) with water forms dimeric [(PhHI2P–)AlH](μ-O) (2) under mild
conditions. Upon reaction of 2 with excess water [(PhHI2P–)Al(OH)](μ-O) (3) is formed with liberation of H2.
创建时间：
2013-11-25
