Hydrogenation of Aldehydes Catalyzed by an Available Ruthenium Complex
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https://figshare.com/articles/dataset/Hydrogenation_of_Aldehydes_Catalyzed_by_an_Available_Ruthenium_Complex/3113173
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资源简介：
A readily
available ruthenium(II) catalyst was developed for the
catalytic hydrogenation of aldehydes with a TON (turnover number)
up to 340000. It can be performed without base and solvent, showing
highly industrial potential. High chemoselectivity can be achieved
in the presence of alkenyl and ketone groups. Further application
of this protocol in glucose reduction showed good efficiency. Theoretical
studies revealed that the rate-determining step is the hydrogenation
step, not the carboxylate-assisted H2 activation step.
创建时间：
2016-03-28
