非活化烯烃和炔烃功能化转化研究数据

非活化烯烃和炔烃功能化转化反应研究数据是由华南理工大学化学与化工学院提供的有关烯烃产物的官能团化研究原始数据，主要记录了铜催化苯腈和2-乙基苯胺合成取代喹唑啉反应，无金属催化合成π共轭喹唑啉-取代乙烯衍生物反应，氧化偶联合成1,5-和1,4,5-取代1,2,3-三唑反应，钯催化伯胺导向的联芳基2-胺C(sp2) -H烷基化反应，，铜催化邻卤苯胺、单质硫和端炔串联环化合成苯并噻唑类化合物反应的数据（包括产物和相关原料的核磁数据，高分辨数据，红外数据等）

Raw data for studies on functional transformation of unactivated alkenes and alkynes was provided by the School of Chemistry and Chemical Engineering, South China University of Technology. This dataset focuses on olefin product functionalization, and mainly records original experimental data from multiple catalytic reactions: 1) copper-catalyzed synthesis of substituted quinazolines from benzonitriles and 2-ethylaniline; 2) metal-free catalytic synthesis of π-conjugated quinazoline-substituted ethylene derivatives; 3) oxidative coupling-based synthesis of 1,5- and 1,4,5-substituted 1,2,3-triazoles; 4) palladium-catalyzed primary amine-directed C(sp²)-H alkylation of biaryl 2-amines; 5) copper-catalyzed tandem cyclization of o-haloanilines, elemental sulfur and terminal alkynes for the synthesis of benzothiazole compounds. The dataset includes characterization data such as nuclear magnetic resonance (NMR) spectra, high-resolution mass spectrometry (HRMS) data, and infrared (IR) spectra for both products and related raw materials.

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背景与挑战

背景概述

该数据集由华南理工大学化学与化工学院提供，聚焦于非活化烯烃和炔烃的功能化转化研究，收录了包括铜催化、无金属催化、氧化偶联和钯催化等多种有机合成反应的原始数据。这些数据涵盖了产物和原料的核磁共振、高分辨质谱及红外光谱等信息，总数据量为587MB，包含2147个文件。