ArXiv论文作者在Figshare上也放了数据集: https://figshare.com/collections/FUMPE/4107803/1
Reactions of (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ir(PMe<sub>3</sub>)(SH)<sub>2</sub> and (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ir(PMe<sub>3</sub>)(SH)(H) with Thionylaniline (PhNSO) to Give Novel Iridium S<sub>3</sub>O and S<sub>2</sub>O Complexes
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https://figshare.com/articles/dataset/Reactions_of_sup_5_sup_-C_sub_5_sub_Me_sub_5_sub_Ir_PMe_sub_3_sub_SH_sub_2_sub_and_sup_5_sup_-C_sub_5_sub_Me_sub_5_sub_Ir_PMe_sub_3_sub_SH_H_with_Thionylaniline_PhNSO_to_Give_Novel_Iridium_S_sub_3_sub_O_and_S_sub_2_sub_O_Complexes/12064941
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资源简介：
Treatment of Cp*Ir(PMe3)(SH)2 (1), where Cp* = η5-C5Me5, with thionylaniline (PhNSO), CS2, and
p-tolylisothiocyanate (p-tolNCS) gave Cp*Ir(PMe3)(S3O) (3), Cp*Ir(PMe3)(S2CS) (4), and Cp*Ir(PMe3)(SH)(SC(S)HN-p-tol) (5), respectively. Treatment of Cp*Ir(PMe2R)(H)(SH) (2a,b), where R = Me (2a),
Ph (2b), with PhNSO gave Cp*Ir(PMe2R)(S2O) (6a,b) as mixtures of interconvertible conformational
isomers. Treatment of 2a with p-tolNCS gave Cp*Ir(PMe3)(H)(SC(S)NH-p-tol) (7). The crystal structures
of 3−5, 6b, and 7 are reported.
创建时间：
2007-08-13
